Adsorption

 

 

A process in which atoms or molecules move from a bulk phase (that is, solid, liquid, or gas) onto a solid or liquid surface. An example is purification by adsorption where impurities are filtered from liquids or gases by their adsorption onto the surface of a high-surface-area solid such as activated charcoal. Other examples include the segregation of surfactant molecules to the surface of a liquid, the bonding of reactant molecules to the solid surface of a heterogeneous catalyst, and the migration of ions to the surface of a charged electrode.

Adsorption is to be distinguished from absorption, a process in which atoms or molecules move into the bulk of a porous material, such as the absorption of water by a sponge. Sorption is a more general term that includes both adsorption and absorption. Desorption refers to the reverse of adsorption, and is a process in which molecules adsorbed on a surface are transferred back into a bulk phase. The term adsorption is most often used in the context of solid surfaces in contact with liquids and gases. Molecules that have been adsorbed onto solid surfaces are referred to generically as adsorbates, and the surface to which they are adsorbed as the substrate or adsorbent.

At the molecular level, adsorption is due to attractive interactions between a surface and the species being adsorbed. The magnitude of these interactions covers approximately two orders of magnitude (8—800 kilojoules/mole), similar to the range of inter­actions found between atoms and molecules in bulk phases. Traditionally, adsorption is classified according to the magnitude of the adsorption forces. Weak interactions ( <40 kJ/mol) analogous to those between molecules in liquids give rise to what is called physical adsorption or physisorption. Strong interactions (>40 kJ/mol) similar to those found between atoms within a molecule (for example, covalent bonds) give rise to chemical adsorption or chemisorption. In physisorption the adsorbed molecule remains intact, but in chemisorption the molecule can be broken into fragments on the surface, in which case the process is called dissociative chemisorption.

The extent of adsorption depends on physical parameters such as temperature, pressure, and concentration in the bulk phase, and the surface area of the adsorbent, as well as on chemical parameters such as the elemental nature of the adsorbate and the adsorbent. Low temperatures, high pressures, high surface areas, and highly reactive adsorbates or adsorbents generally favor adsorption.

Adsorption is directly applied in processes such as filtration and detergent action. Adsorption also plays an important role in processes such as heterogeneous catalysis, electrochemistry, adhesion, lubrication, and molecular recognition. In heterogeneous catalysis, gas or solution-phase molecules adsorb onto the catalyst surface, and reac­tions in the adsorbed monolayer lead to products which are desorbed from the surface. In electrochemistry, molecules adsorbed to the surface of an electrode donate or accept electrons from the electrode as part of oxidation or reduction reactions. In adhesion and lubrication, the chemical and mechanical properties of adsorbed monolayers play a role in determining how solid surfaces behave when in contact with one another. In biological systems, the adsorption of atoms and molecules onto the surface of a cell membrane is the first step in molecular recognition.

 

 

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