Compounds with large three-dimensional molecular struc­tures containing ether chains linked by three-coordinate nitrogen atoms. Thus cryptands are macropolycyclic polyaza-polyethers. For example, the compound (2,2,2)-cryptand has three chains of the form -CH2CH2OCH2CH2OCH2CH2-.

These chains are linked at each end by a nitrogen atom. Cryptands, like the *crown ethers, can form coordi­nation complexes with ions that can fit into the cavity formed by the open three-dimensional structure, i.e. they can ‘cryptate’ the ion. Various types of cryptand have been produced hav­ing both spherical and cylindrical cavities. The cryptands have the same kind of properties as the crown ethers and the same uses. In general, they form much more strongly bound complexes and can be used to stabilize unusual ionic species. For example, it is possible to produce the negative Na- ion in the compound [(2,2,2)-cryptand-Na]+Na-, which is a gold-coloured crystalline substance stable at room temperature. Cluster ions, such as Pb52-, can be similarly stabilized.



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